Catalytic dealkylation of phosphates with binuclear boron compounds.
| Author | |
|---|---|
| Abstract |
:
The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate. |
| Year of Publication |
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2002
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| Journal |
:
Journal of the American Chemical Society
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| Volume |
:
124
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| Issue |
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9
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| Number of Pages |
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1864-5
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| Date Published |
:
2002
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| ISSN Number |
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0002-7863
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| URL |
:
https://doi.org/10.1021/ja017360m
|
| DOI |
:
10.1021/ja017360m
|
| Short Title |
:
J Am Chem Soc
|
| Download citation |
